All but one of the following compounds react with aniline to give acetanilide. Which one does not?

Which of the following sets of reagents, used in the order shown, would enable the preparation of $p$-chlorophenol from $p$-chloronitrobenzene?

Given below are two statements:
Statement $I$: The dipole moment of $R-CN$ is greater than $R-NC$ and $R-NC$ can undergo hydrolysis under acidic medium to produce $R-NH_2$ and $HCOOH$.
Statement $II$: $R-CN$ hydrolyses under acidic medium to produce a compound which on treatment with $SOCl_2$ followed by the addition of $NH_3$ gives another compound $(x)$. This compound $(x)$ on treatment with $NaOCl/NaOH$ gives a product,that on treatment with $CHCl_3/KOH/\Delta$ produces $R-NC$.
In the light of the above statements,choose the correct answer from the options given below:

The compounds $X$ and $Y$ are respectively:

$A$ colourless substance $'A'$ $(C_6H_7N)$ is sparingly soluble in water and gives a water-soluble compound $'B'$ on treating with mineral acid. On reacting with $CHCl_3$ and alcoholic potash,$'A'$ produces an obnoxious smell due to the formation of compound $'C'$. Reaction of $'A'$ with benzenesulphonyl chloride gives compound $'D'$ which is soluble in alkali. With $NaNO_2$ and $HCl$,$'A'$ forms compound $'E'$ which reacts with phenol in an alkaline medium to give an orange dye $'F'$. Identify compounds $'A'$ to $'F'$.

The ammonolysis of alcohol is represented by the reaction $xCH_3OH + yNH_3 \xrightarrow[Al_2O_3/ThO_2]{300-400^{\circ}C} \text{Products}$. The products formed are: